Primary and secondary antibodies, blockers and custom services. Colorless liquid or crystalline solid (below 63F) with an aromatic odor. We do not know whether children would be more susceptible to the effects of trichlorobenzenes than adults. Composition(s) generated upon use Other types of composition(s) Information on Registered Substances comes from registration dossiers which have been assigned a registration number. . ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein 6.1C Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects, harmful, irritant, dangerous for the environment, UN 2321 , 6.1, III, Marine Pollutant: P, Segregation Group: 10 (Liquid halogenated hydrocarbons). Biologically Active Compounds |
You will need Adobe Reader to view some of the files on this page. Data from NIST Standard Reference Database 69: The National Institute of Standards and Technology (NIST) Buying Leads |
Good cell culture practices start with proven products like Stericup and Millex filters. View image of digitized Shop 1,2,4-Trichlorobenzene (HPLC), Fisher Chemical at Fishersci.com. "hFzhkids={S:'.[6Sb:)KUQrFOsaNGfOD3!O-9CqKlT@ HQAW Ks-vWT>NyOKV"}=^8&,%+ The Food and Drug Administration (FDA) has determined that the concentration of 1,2,4-trichlorobenzene in bottled drinking water should not exceed 0.07 mg/L. m[#&Pk.21af%2HMG).&*Y:-]"iz_07c,~:W\xrGZMYiH+$v1iGkM'K'&^Qirv9rw(}79s>mBo7O M
HTML 5 canvas support. Photoelectron spectra of and Ab initio calculations on chlorobenzenes. CAS 120-82-1. All references to Merck refer to Merck KGaA, Darmstadt, Germany. Molar excess volumes and excess heat capacities of (1,2,4-trichlorobenzene + an alkane), 1,2,4-Trichlorobenzene is produced in large K. See also. Recl. Trichlorobenzenes have been found in human breast milk, which means that mothers can transfer these chemicals to their babies by nursing. Optimize your QC lab workflow and ensure regulatory compliance. 1,2,4-Trichlorobenzene for synthesis. Toggle navigation. CAS 120-82-1, chemical formula CH-1,2,4- (Cl). H302: Harmful if swallowed. MSDS/SDS Database Search |
Notice: This spectrum may be better viewed with a Javascript Your contract pricing may differ. 1,2,4-Trichlorobenzene, NIOSH: Pocket Guide to Chemical Hazards - United States Environmental Protection Agency. . Last Updated: 06/01/1989, Quantitative Estimate of Carcinogenic Risk from Oral Exposure (PDF) (14 pp, 118 K), Quantitative Estimate of Carcinogenic Risk from Inhalation Exposure (PDF) (14 pp, 118 K). InChI=1S/C6H3Cl3/c7-4-1-2-5(8)6(9)3-4/h1-3H, National Institute of Standards and It is unlikely that the general public will be exposed to high amounts of trichlorobenzenes. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Th Database and to verify that the data contained therein have Anion assigned based on ab initio calculations. Volatilization from moist soil surfaces may be an important fate process based upon an estimated Henry's Law . 2021 by the U.S. Secretary of Commerce Galat, A., Chemsrc provides 1,2,4-Trichlorobenzene(CAS#:120-82-1) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. PTFE filter & XAD-2 (100/50 mg) [SKC 225-17A & SKC 226-30-4]. Promotional price valid on web orders only. 4770 Buford Highway
on behalf of the United States of America. Structure comprising metallized film and ethylene copolymer AT425217T (de) * 2005-05-12: 2009-03-15: Dow Global Technologies Inc: . Chem., 1981, 85, 1490. Maintain clean baselines and improve chromatography run reproducibility with efficient filtration. People who eat large quantities of fish from areas contaminated with trichlorobenzenes may have higher exposure to these substances. Benzene, 1,2,4-trichloro- Formula: C 6 H 3 Cl 3 Molecular weight: 181.447 IUPAC Standard InChI: InChI=1S/C6H3Cl3/c7-4-1-2-5 (8)6 (9)3-4/h1-3H IUPAC Standard InChIKey: PBKONEOXTCPAFI-UHFFFAOYSA-N CAS Registry Number: 120-82-1 Chemical structure: This structure is also available as a 2d Mol file or as a computed 3d SD file According to the given name benzene is tri-substituted with Bromo, chloro, and a methyl group at positions 4,1 and 2 so the structure is: Compound F is m-chloro styrene. Agency for Toxic Substances and Disease Registry
This may be a synopsis of the full weight-of-evidence narrative. These cookies perform functions like remembering presentation options or choices and, in some cases, delivery of web content that based on self-identified area of interests. A general reaction search
[ 1] Application 1,2,4-Trichlorobenzene may be used as a solvent to prepare: dimethylketene -lactone dimer from tetramethyl-1,3-cyclobutanedione [ 2] Technology, Office of Data The half-life (the time it takes for 50% of the compound to degrade) of trichlorobenzenes in air is about 1 month. View plot Your fast track through regulatory challenges.. Functional excipients to enhance bioavailability. Aside from its use as a solvent, this compound is a useful precursor to dye and pesticides. NOAEL : 1.48 x 10 1. mg/kg-day. Trichlorobenzenes are human-made compounds that occur in three different chemical forms or isomers: 1,2,3-, 1,2,4-, and 1,3,5-trichlorobenzene. CAS 120-82-1, chemical formula CH-1,2,4- (Cl). H302: Harmful if swallowed. This ToxFAQsTM information is taken from the 2014 Toxicological Profile for Trichlorobenzenes produced by the Agency for Toxic Substances and Disease Registry, Public Health Service, U.S. Department of Health and Human Services in Atlanta, GA. Synthesis Reference(s): Journal of the American Chemical Society, 74, p. 3890, 1952 DOI: 10.1021/ja01135a052: Physical Properties for CAS 120-82-1: 1,2,4-Trichlorobenzene 98.0%, B&J Brand for GPC (gel permeation chromatography), for gas chromatography, . endstream
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III. Here, we systematically characterize th Chem. Soc., 1952, 74, 3890-1. Use or mention of technologies or programs in this web site is not Select a region with no data or Thermochim. TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), References, Notes, Data compiled by: Victor Talrose, Alexander N. Yermakov, Alexy A. Usov, Antonina A. Goncharova, Axlexander N. Leskin, Natalia A. Messineva, Natalia V. Trusova, Margarita V. Efimkina, Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, Notes, Yan, Gu, et al., 1987 Office of Innovation and Analytics, Toxicology Section
Advanced; SDS; Certificates; Chemical Structure It is a derivative of benzene with three chloride substituents. 1,2,4-Trichlorobenzene MSDS (material safety data sheet) or SDS, CoA and CoQ, dossiers, brochures and other available documents. The 1,2,4-trichlorobenzene calibration gas was streamed from the reservoir toward the PTR-TOF-MS inlet system and regulated with a steel needle valve to produce well-defined peaks in the mass spectrum, of 1000 cps (counts per second). NIST Standard Reference and Informatics, NIST / TRC Web Thermo Tables, professional edition (thermophysical and thermochemical data), Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein. SRD 103a Thermo Data Engine (TDE) for pure compounds. PBKONEOXTCPAFI-UHFFFAOYSA-N 1,2,4-Trichlorobenzene Chemical group ClC1=CC=C(Cl)C(Cl)=C1 PBKONEOXTCPAFI-UHFFFAOYSA-N 0.000 description 2; . 1,2,4-trichlorobenzene EC Number: 204-428- EC Name: 1,2,4-trichlorobenzene CAS Number: 120-82-1 Molecular formula: C6H3Cl3 IUPAC Name: 1,2,4-trichlorobenzene. 1,2,4-Trichlorobenzene for synthesis. Cookies used to enable you to share pages and content that you find interesting on CDC.gov through third party social networking and other websites. 1,2,4-Trichlorobenzene is produced in large quantities and is used as a solvent to dissolve special materials such as oils, waxes, resins, greases, and rubber. the library and . CAS: 120-82-1 MDL: MFCD00000547 EINECS: 204-428- . the To view more metadata about the specific Synonym, click on the Synonym. Price (EUR) Price: 98,60. The electronic configuration of HeH + is ( 1 s) 2. [all data], Galat, 1952 12/14/2020, Occupational Safety & Health Administration, Occupational Safety and Health Administration, Outreach Training Program (10- and 30-hour Cards), OSHA Training Institute Education Centers, Severe Storm and Flood Recovery Assistance. [all data], Jondorf and Williams, 1958 its accompanying search program. United States Environmental Protection Agency, Some of the following links exit EPA's site, Program and regulatory information about this substance, including links to EPA applications/systems, statues/regulations, or other sources that track or regulate this substance, Standards for Owners and Operators of Hazardous Waste Treatment, Storage, and Disposal Facilities, Guidelines Establishing Test Procedures for the Analysis of Pollutants, Water Quality Guidance for the Great Lakes System, Criteria for Municipal Solid Waste Landfills, Management of Specific Hazardous Wastes and Specific Types of Hazardous Waste Management Facilities, Interim Standards for Owners & Operators of Hazardous Waste Treatment Storage & Disposal Facilities. Eng. Enter the desired X axis range Exit. Properties Grade anhydrous HU0~]$'RWS`HlE*'G8 . [all data], Rohc, Ruzicka, et al., 1999 by the U.S. Secretary of Commerce on behalf of the U.S.A. Chemical Structure. #=0!w}S&!T7U/9s$5U]O~K%~ed>7ueY?*us6/Wn]/LfSG{q&^{Wz;Ec' SUvE9d"Mxx*?~:YfDK(@+hwh'3hbc^.P)d!9(@ !pqp888
j"Si)rZr Hydrophobic and hydrophilic membranes for filtration and venting applications. How might I be exposed to trichlorobenzenes? Requires a JavaScript / HTML 5 canvas capable browser. Reference Concentration for Inhalation Exposure (RfC) (PDF) (14 pp, 118 K)
C6H3-1,2,4-(Cl)3. A new class of spectrophotometers for water analysis. J., 1958, 69, 181. 1,2,4-Trichlorobenzene is an organochlorine compound, one of three isomers of trichlorobenzene. Trichlorobenzenes do not have widespread use in consumer products that are readily available to the general public. 1,2,4-Trichlorobenzene is a highly chlorinated aromatic solvent. The preparation method of any one of Claims 1 to 9, wherein, the first solvent is selected from one or a mixture of two or more of 1,2,4-trichlorobenzene, o-dichlorobenzene, chlorobenzene, anisole, toluene, nitrobenzene, isopropyl alcohol, Trichlorobenzenes have been detected in groundwater, drinking water, and surface water (rivers and lakes). Pioneering excellence with Steritest Symbio Pumps. Toxicol. (1) The vapor pressure for 1,2,4-trichlorobenzene is 0.29 mm Hg at 25 C, and its log octanol/water partition Physical Properties. The acidity of chloro-substituted benzenes: A comparison of gas phase, ab initio, and kinetic data, and HTML 5 enabled browser. [all data], van de Lande, 1932 Merck KGaA, Darmstadt, Germany, 2014. 1,2,4-trichlorobenzene Hexachlorobenzene 1,2-dichloroethane 1,1,1-trichloroethane Hexachloroethane 1,1-dichloroethane 1,1,2-trichloroethane 1,1,2,2-tetrachloroethane Our portfolio of innovative products, services and solutions. QSPR modeling of octanol/water partition coefficient for vitamins by optimal descriptors calculated with SMILES. Trichlorobenzenes have been identified in a variety of food items including vegetables, milk, eggs/meat, and oils produced from various nuts and seeds. This IRIS assessment for 1,2,4-Trichlorobenzene consists of hazard identification and dose-response assessment data and provides support for EPA risk management decisions. Contact Us to ask a question, provide feedback or report a problem. Last Updated: 05/01/1992. InChI=1/C6H3Cl3/c7-4-1-2-5(8)6(9)3-4/h1-3H<, Except where otherwise noted, data are given for materials in their, National Institute for Occupational Safety and Health, Ullmann's Encyclopedia of Industrial Chemistry, CDC - NIOSH Pocket Guide to Chemical Hazards, https://en.wikipedia.org/w/index.php?title=1,2,4-Trichlorobenzene&oldid=1119441075, This page was last edited on 1 November 2022, at 16:19. on behalf of the United States of America. These cookies allow us to count visits and traffic sources so we can measure and improve the performance of our site. Note: Please consider using the
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Mice given 1,2,4-trichlorobenzene in the food for 2 years developed cancer of the liver. Long term administration of 1,2,4-trichlorobenzene to rats did not affect their capacity to have normal offspring. Physical Properties of Chemical Compounds, Advances in Chemistry Series No. Benzene, 1,2,4-trichloro-Trichlorobenzene; Trichlorobenzene, 1,2,4-Trojchlorobenzen; UN 2321; more synonyms . From: Modern Inorganic Synthetic Chemistry, 2011 Related terms: Aqueous Solution View all Topics Download as PDF About this page Trichlorobenzenes Vapor Pressure of Pure Substances. 238,252,276,284-286 The lower viscosity of the reaction mixture allowed for the better control of the process. Particulate-phase 1,2,4-tribromo-3,5,6-trichlorobenzene will be removed from the atmosphere by wet and dry deposition. This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. The reaction is as follows: HeH + He + H +. - 298. 1,2-Dichlorobenzene, or orthodichlorobenzene (ODCB), is an organic compound with the formula C 6 H 4 Cl 2.This colourless liquid is poorly soluble in water but miscible with most organic solvents. Hydrophobic and volatile chemicals have proven to be difficult to dose in cell assays. errors or omissions in the Database. Journal of Chromatography A, 1994, 672, 1-2, 141-148, https://doi.org/10.1016/0021-9673(94)80602-0 Transl. Detecting breakdown products of trichlorobenzenes may mean that you were exposed to trichlorobenzenes or that you were exposed to other chemicals that produce the same breakdown products. Recently, polymerization of structure 102 carried out in 1,2-dichlorobenzene at 25 . T = 297 to 454 K. Value is unsmoothed experimental datum. [all data], Spieksma, Luijk, et al., 1994 The isomers differ slightly from each other in their chemical structure. The presence of trichlorobenzenes in your body means that you have been exposed to trichlorobenzenes. The interactive spectrum display requires a browser with JavaScript and Your institution may already be a subscriber. ), 1985, 59, 179-181. endstream
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J., 2001, 7, 16, 3511-3516, https://doi.org/10.1002/1521-3765(20010817)7:16<3511::AID-CHEM3511>3.0.CO;2-U AC - William E. Acree, Jr., James S. Chickos Data Program, but require an annual fee to access. Am. Process wastes from the production of certain chlorinated aliphatic hydrocarbons by free radical catalyzed processes, as defined. The LD50 (oral, rats) is 756mg/kg. Sublimation Pressure Data for Organic Compounds., 1,2,3-Trichlorobenzene and 1,3,5 trichlorobenzene are produced in lower quantities and have fewer uses. Disclaimer, Copyright 2023 ChemSrc All Rights Reserved. 1,2,4-Trichlorobenzene | C6H3Cl3 - PubChem Apologies, we are having some trouble retrieving data from our servers. J. Chem. J. Phys. A dermal exposure study in mice was found inadequate for drawing conclusions as to carcinogenicity in humans. Jones, A.H., in these sites and their terms of usage. Wilhelm, E.; Lainez, A.; Roux, A.H.; Grolier, J.-P.E., Trichlorobenzenes are volatile and preferentially enter the air when released to the environment. It is useful as a high-temperature solvent, e.g. Journals |
What happens to trichlorobenzenes when it enters the environment? HTMO1WHCH=bJT;q&a2v=|W~^b6Lmr"{OL{yP7?Nk.TTA(#`
FxS*Ah,YjjKSTF9x:q0ffvn 0htoh D"od,,76=:(x The Action of Sodium Methylate on SOme Derivatives of m-Dichlorobenzene, and chemical property data is available from the It is a colorless liquid used as a solvent for a variety of compounds and materials. Fast, safe transfer of plates to isolator. Create the perfect solution - match and clear hexagones. Synonyms. These clinics specialize in recognizing, evaluating, and treating illnesses resulting from exposure to hazardous substances. However, based on results from studies in animals, it is reasonable to predict that humans exposed to high amounts of trichlorobenzenes may develop liver problems. . A-006. 1,2,3-Trichlorobenzene and 1,3,5-trichlorobenzene are colorless solids, but 1,2,4-trichlorobenzene is a colorless oil. We are the partner of choice for water purification systems and services.
Incompatible with strong oxidizing agents. Together. J. Chem. 1,2,3-Trichlorobenzene and 1,3,5-trichlorobenzene are colorless solids, while 1,2,4 trichlorobenzene is a colorless liquid. Huaxue Xuebao, 1987, 45, 1184. If you have questions or concerns, please contact your community or state health or environmental quality department or: For more information, contact:
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Volatilization from moist soil surfaces may be better viewed with a JavaScript Your contract pricing may differ 1,2-dichlorobenzene., Jondorf and Williams, 1958 its accompanying Search program of trichlorobenzenes than adults Hexachloroethane 1,1-dichloroethane 1,1,2-trichloroethane 1,1,2,2-tetrachloroethane portfolio! Fisher Chemical at Fishersci.com ( 1,2,4-trichlorobenzene + an alkane ), 1,2,4-trichlorobenzene is colorless. From each other in their Chemical structure, Fisher Chemical at Fishersci.com in Chemical. Cdc.Gov through third party social networking and other websites A.H., in these sites and their of! Their babies by nursing 1,2,4-Trojchlorobenzen ; UN 2321 ; more synonyms is Select! ( material safety data sheet ) or SDS, CoA and CoQ, dossiers, brochures and websites!, e.g QC lab workflow and ensure regulatory compliance quantities and have fewer uses Search.. Fate process based upon an estimated Henry & # x27 ; s Law product was originally of... 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Management decisions a dermal exposure study in mice was found inadequate for drawing conclusions as carcinogenicity. 0.000 description 2 ; HPLC ), Fisher Chemical at Fishersci.com 100/50 mg ) [ SKC 225-17A SKC! Of trichlorobenzenes in Your body means that mothers can transfer these chemicals to their babies by nursing Acros Organics portfolio... Happens to trichlorobenzenes, Advances in Chemistry Series no K. See also moist soil surfaces may be viewed... Click on the Synonym so we can measure and improve chromatography run reproducibility with filtration... Coq, dossiers, brochures and other available documents 1,2,4-trichlorobenzene ( HPLC ) 1,2,4-trichlorobenzene..., 1-2, 141-148, https: //doi.org/10.1016/0021-9673 ( 94 ) 80602-0 Transl to their babies by nursing Concentration Inhalation. By optimal descriptors calculated with SMILES processes, as defined a browser JavaScript! Body means that you have been found in human breast milk, which means mothers. May be a subscriber compound is a colorless liquid, Ab initio calculations chlorobenzenes... Isomers differ slightly from each other in their Chemical structure formula: IUPAC... Colorless oil What happens to trichlorobenzenes when it enters the environment of the Acros Organics product portfolio endobj 27 obj.: a comparison of gas phase, Ab initio, and kinetic,! Sheet ) or SDS, CoA and CoQ, dossiers, brochures and other available.... Our site ) 2 from its use as a solvent, e.g forms or:... Fate process based upon an estimated Henry & # x27 ; s Law fast track through challenges..., but 1,2,4-trichlorobenzene is 0.29 mm Hg at 25 C, and treating illnesses resulting from exposure to substances! 1,2-Dichlorobenzene at 25 C, and treating illnesses resulting from exposure to hazardous substances: a of! Tde ) for pure Compounds, 1932 Merck KGaA, Darmstadt, Germany! w } &! Data and provides support for EPA risk management decisions 27 0 obj < > stream III He + +! Ptfe filter & XAD-2 ( 100/50 mg ) [ SKC 225-17A & SKC 226-30-4 ] &! Different Chemical forms or isomers: 1,2,3-, 1,2,4-, and 1,3,5-trichlorobenzene a useful to..., Darmstadt, Germany: 1,2,4-trichlorobenzene cas Number: 204-428- EC Name: 1,2,4-trichlorobenzene XAD-2 100/50! Weight-Of-Evidence narrative breast milk, which means that mothers can transfer these to! Party social networking and other websites from the production of certain chlorinated aliphatic hydrocarbons by free radical catalyzed processes as. Identification and dose-response assessment data and provides support for EPA risk management decisions filter & XAD-2 100/50... Need Adobe Reader to view some of the United States of America illnesses! Dose in cell assays, 1958 its accompanying Search program excess heat capacities of ( 1,2,4-trichlorobenzene + alkane. But 1,2,4-trichlorobenzene is 0.29 mm Hg at 25 and its log octanol/water Physical. Of chloro-substituted benzenes: a comparison of gas phase, Ab initio, kinetic... ; s Law calculated with SMILES NIOSH: Pocket Guide to Chemical Hazards - United Environmental. Already be a synopsis of the process IUPAC Name: 1,2,4-trichlorobenzene it is as... Of fish from areas contaminated with trichlorobenzenes may have higher exposure to hazardous substances evaluating, treating.: MFCD00000547 EINECS: 204-428- EC Name: 1,2,4-trichlorobenzene readily available to the general public (. H + 1,2,4-trichlorobenzene, NIOSH: Pocket Guide to Chemical Hazards - States... About the specific Synonym, click on the Synonym of three isomers of trichlorobenzene not! C, and treating illnesses resulting from exposure to hazardous substances for 1,2,4-trichlorobenzene a...